Simulation of hydrogen production for mobile fuel cell. After the initial reforming reaction, the steam undergoes a watergas shift reaction, which converts carbon monoxide co into. Steam methane reforming, or smr, processes feedstocks, ranging from natural gas to light naphtha, mixed with steam to produce a hydrogen rich syngas effluent, with a typical h 2 co ratio of 3. Inside a proprietary topfired steam reformer, the feed gas and steam are then heated at pressures of 15 45 barg to generate hydrogen, carbon monoxide and carbon dioxide. Steam methane reforming smr and autothermal reformer atr are two industrial examples of the primary and secondary reformers, respectively. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane reforming smr. Distributed production of hydrogen from natural gas utilizes small scale steam methane reforming technology. Use features like bookmarks, note taking and highlighting while reading production of synthesis gas by steam methane reforming. Steam reforming before development of psa with a polybed psa system, the co 2 removal system and methanator become redundant. Simulation of air cooled heat exchanger using unisim hysys.
Sulfur deactivation effects on catalytic steam reforming of. Steam methane reforming simulation hydrogen production hysys tutorial. Conventional steam reforming catalysts are nibased catalysts with 1020 wt. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane. Steam methane reforming is the most common and economical way to make hydrogen. On the other hand, the process of combined reforming utilizes both of primary and secondary tools for production of synthesis gas, as it is commonly practiced in ammonia manufacturing. Production of synthesis gas by steam methane reforming. Given the intrinsic kinetics, the tortuosity factor of a nimgal 2 o 4 catalyst was determined under reaction conditions by minimizing the sum of squares of residuals of the exper. This model predicts the reforming process for a variety of feed stocks and reformer con. Steam methane reforming simulation hydrogen production hysys.
Services the reformer process design is performed with a proprietary incremental kinetic model, and re. Distributed hydrogen production via steam methane reforming. The experimental study has been done in a plug flow reactor under a near atmospheric pressure 1. In recent years, hydrogen h 2 has gained much research emphasis as an energy carrier due to its environmental friendliness and wide range of energy applications. Water enters the furnace, producing steam at a very high temperature. Steam methane reforming smr is a process in which methane from natural gas is heated, with steam and a catalyst, to produce synthetic fuel. Steam methane reforming simulation hydrogen production. Industrial gases desktop software is a strategic set of 45 intelligent, preprogrammed modules created to benefit anyone using, producing or supplying any of the major 9 industrial gases by. Please guide me with the techniques used and references available. For this purpose, methane was used the starting point and building block for the progressive understanding of reforming of complex hydrocarbons.
The results show that larger cylinder radius can promote reforming reaction. Mar 30, 2015 steam reforming of methane steam reforming of methaneitso chen october 24, 2010submitted as coursework for physics 240, stanford university, fall 2010. Effect of catalytic cylinders on autothermal reforming of. Carbon monoxide is reacted downstream in two, high and lowtemperature. Steam reforming of propane can be viewed as producing co and h 2 by equation, followed by production of methane by equation, with the propane completely consumed within a very short distance above the distributor, and the water gas shift equation, and methane steam reforming equations, reactions taking place in the bulk of the fbmr.
The methane steam reforming was studied by 26 in a fixed bed tubular quartz micro reactor with cobalt catalyst. High levels of purity can be reached by employing inhouse pressure swing adsorption purification technology. Smr is a costeffective and energy efficient way of producing hydrogen. Steam methane reforming hydrogen production hysys tutorial. Modeling and simulations of steam methane reforming smr process to produce hydrogen and or syngas are presented in this article. Methane steam reforming reaction behaviour in a packed bed. Sometimes referred to as steam methane reforming smr, this process involves the heating of methane ch4 with steam, in the presence of a catalyst, to create hydrogen h2 and carbon oxide byproducts. Kinetic based simulation of methane steam reforming and water gas shift for hydrogen production using aspen plus article pdf available in chemical engineering transactions 56. The metal sulfur bond is so strong that catalytic activity is substantially reduced, even at extremely low ppb levels gasphase concentrations of hydrogen sulfide,4,5 although several models have been purposed to address methane steam reforming reactions,6. The advantages of distributed hydrogen production are the production unit can be located at the consumer refueling site, the unit capacity can be tailored to the sites fueling requirements, and this approach eliminates the need for an extensive hydrogen delivery infrastructure. Steam reforming of propane in a fluidized bed membrane. Steam methane reforming of natural gas or naphtha is the most widely used process for commercial production of hydrogen. Steam methane reforming simulation hydrogen production hysys tutorial p sims.
Leaving the shift reactor, the gas contains approximately 75 vol% hydrogen, with carbon dioxide, carbon monoxide and some unconverted methane plus nitrogen if this was present in the feed to the. Steam methane reforming hydrogen production air liquide. The rising number of petrochemical complexes and refineries in the region, the steam methane reforming market is forecast to pick up pace in asia pacific in the coming years. Aspen hysys 2006 provides tool to design a steady and dynamics state. In the overall steam methane reforming smr reaction, methane reacts with steam at high temperatures and moderate pressures in catalystfilled tubes to generate synthesis gas, a mixture of hydrogen, carbon monoxide and some carbon dioxide.
The endothermic steam reforming reaction absorbs heat from the gas. An experimental and modelling study of the pyrolysis and of the steam reforming of methane in mixtures representative of a gas produced from biomass gasification has been performed. Methane steam reforming reaction behaviour in a packed. If anyone is working with modelling of steam methane reforming with. Methane steam reforming for synthetic diesel fuel production. The resultants of the reaction include hydrogen, carbon monoxide and. The tubular reactor design for a steam reformer in figure 1 a schematic representation of a hydrogen production system on the basis on methane conversion is shown. Simulation, sensitivity analysis and optimization of. Steam methane reforming overview of steam methane reforming. Steam methane reforming posted in chemical process simulation. The main purpose of this technology is hydrogen production. Steam reforming of methane in a synthesis gas from biomass. Kinetics, catalysis and mechanism of methane steam reforming.
Smr runs were conducted at various operation parameters. Thermodynamic analysis of steam reforming of methane has been studied by method of gibbs free energy minimization for hydrogen or syngas production in the ranges of steam to methane from 0. Jul 10, 2010 industrial gases desktop software is a strategic set of 45 intelligent, preprogrammed modules created to benefit anyone using, producing or supplying any of the major 9 industrial gases by. Stabilize steam methane reformer combustion, reduce variability, and gain control of energy costs with emersons steam methane reformer solution, which will enable your operators to respond to changing conditions, keep your equipment from degrading and failing, and help stabilize your reformers performance. This reforming process operates at very high severity where the reaction temperatures are in the range of 850950 deg c and pressures in the range of 2030 bar. Steam reacts with natural gas, producing hydrogen and carbon monoxide. Download it once and read it on your kindle device, pc, phones or tablets. Advanced modelling and optimisation of natural gas reforming. The model of the steam reforming process used was developed using equilibrium reactor type. An equilibrium or gibbs reactor is appropriate or the smr reactor and one or two additional equilibrium reactors for the shift reactors. A conventional methane reforming based hydrogen production plant can be.
Hydrogen from natural gas via steam methane reforming smr. A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst. Regionally, asia pacific is currently occupying the majority share in the global steam methane reforming market. Assessment of co2 capture options from various points in. Steam methane reformers hydrogen ammonia methanol syngas gtl bd energy systems have executed more than 90 steam methane reformer projects which include lumpsum revamp and turnkey epc projects and cover a full range of equipment supply and services. Dec 16, 2008 steammethane reforming smr reaction was studied using a tubular reactor packed with nio. Using hysys, you can model and simulate the steam ethane reforming with propylene very easy. The hydrogen produced contains less than 10 ppmv of carbon oxides, but can achieve only a hydrogen concentration between 92 and 97 vol% depending on the severity of the reforming reaction. The reaction is strongly endothermic consumes heat. Smr based plants are most commonly used to produce a hydrogen product or a combination of a hydrogen stream and another syngas product.
Steam methane reforming chemical process simulation. Methane steam reforming an overview sciencedirect topics. Concentrating solar power library, user manual, graz, 2016, search pubmed. Integration of methane steam reforming and water gas shift. Steam methane reforming smr is a major hydrogen production process with more than 70 years of history. The reduced computational time with high model validity is the. The steam reforming of methane srm is a fieldproven technology for. Get your team aligned with all the tools you need on one secure, reliable video platform. Jul 29, 20 contents steam reforming reactions steam reforming catalysts equilibrium considerations equilibrium curves effect of process variables carbon formation poisoning steam reformer modelling preand postreforming 27. In the water shift reactor, carbon monoxide and steam react to form carbon dioxide and more hydrogen gas. The steam methane reforming process can be broken down into five distinct steps. Methane steam reforming consists in the reaction of methane and steam on a supported nickel catalyst to produce a mixture of h 2, co, co 2 and ch 4. Steam methane reforming primarily involves two reactions.
Jul 28, 20 equilibrium considerations both reforming and shift reactions are reversible rate of shift is fast compared to reforming methane conversion favoured by. Steammethane reforming the global syngas technologies council. What is the best aspen plus model for simulation of steam. In addition to the maturity of the technology, natural gas reforming is also the most economical among all hydrogen production pathways. Steam methane reforming smr is currently the main hydrogen production process in industry, but it has high emissions of co 2, at almost 7 kg co 2 kg h 2 on average, and is responsible for about 3% of global industrial sector co 2 emissions. Process analysis of solar steam reforming of methane for producing. Under these conditions, the catalyst presents the average h2co. May 19, 2011 steam methane reforming simulation hydrogen production hysys tutorial p sims.
The catalyst showed stability and activity at a feed molar ratio sc21, wf 0. Both steam reforming process model with and without mixer were developed and simulated in aspen plus environment. You can easily model the steammethane reformer smr using the hysys software or aspenplus from apsen technologies corporation. Steam methane reforming syngas production air liquide. Steps of designging a steam methane reformer for syngas production. Steammethane reforming smr reaction was studied using a tubular reactor packed with nio.
It consists of a reformer with multiple additional components for pre and post processing. Co are also active for the methane steam reforming 25. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. Al2o3 catalyst to obtain synthesis gases with h2co ratios optimal for the production of synthetic diesel fuel from steamhydrogasification of carbonaceous materials.
Advanced modelling and optimisation of natural gas. Fbcr was used for detailed modelling of the catalyst beds considering rigorous intraparticle mass and heat transport. In smr, methane reacts with steam under 325 bar pressure 1 bar 14. Steam reforming of natural gas wikid energy funhouse. Hydrogen production by steam reforming chemical engineering. This paper presents the kineticbased simulation of methane steam reforming msr from natural gas and water gas shift wgs reaction for hydrogen.
Atr is essentially an oxidative steam reforming, which. Heat and power integration of methane reforming based hydrogen. After the reformation process, the new gas stream undergoes a water gas shift wgs to react the carbon monoxide with steam, in the presence of a catalyst, which creates more hydrogen and converts the carbon monoxide into. Methane steam reforming, methanation and watergas shift. May 14, 2010 steammethane reforming is a process in which high temperature steam 700c c is reacted with a methane source usually natural gas at a high pressure of 325 bar with a catylist. Pdf kinetic based simulation of methane steam reforming. Water gas shift reaction and the reforming reaction. Videos you watch may be added to the tvs watch history and. Thermodynamic analysis of steam reforming of methane with. Steam methane reformers remain our core market with our engineers having extensive experience encompassing process design, detailed design, and construction expertise of all major technology licensors. May 01, 2010 in the overall steam methane reforming smr reaction, methane reacts with steam at high temperatures and moderate pressures in catalystfilled tubes to generate synthesis gas, a mixture of hydrogen, carbon monoxide and some carbon dioxide. In energy, smr is the most widely used process for the generation of hydrogen 2 if playback doesnt begin shortly, try restarting your device. The gproms advanced model library for fixedbed reactors aml. Bd energy systems have executed more than 90 steam methane reformer projects which include lumpsum revamp and turnkey epc projects and cover a.
Sulfur deactivation effects on catalytic steam reforming. Methane steam reforming has been simulated, analyzed and optimized with the aid of aspen plus, in this work. The resultants of the reaction include hydrogen, carbon monoxide and a relatively small amount of carbon dioxide. Steam reforming of methane steam reforming of methaneitso chen october 24, 2010submitted as coursework for physics 240, stanford university, fall 2010. Methane steam reforming in industry is carried out in a catalytic multitubular fixedbed. Process simulation to obtain a synthesis gas with high concentration of hydrogen 31 the addition of steam in the second reactor serves to the dual purpose of maintaining the reactor temperature and either to ensure that the excess of methane from the natural gas stream is consumed. Single step compact steam methane reforming process for hydrogencng hcng production from natural gas badhe r. Aspen hysys flowsheeting environment, the highly nonlinear sofc. Here, the results are reported of an investigation of the effect of steamtocarbon ratio sc on co 2 capture criteria from various locations in the.
Simulation of methane slippage in steam methane reforming mohd. Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. Contents steam reforming reactions steam reforming catalysts equilibrium considerations equilibrium curves effect of process variables carbon formation poisoning steam reformer modelling preand postreforming 27. Pure ch4 and ch4co2 mixtures were used as reactants in the presence of steam. Redefining steam methane reformer performance in hydrogen.
Figures 2 and 3 show examples of curves of total methane conversion and of conversion of methane into c02 vs. Steam and hydrocarbon enter the reactor as feedstock, and hydrogen and carbon dioxide are generated at the end of the process. Kinetic based simulation of methane steam reforming and. A new multicylinder microchamber reactor is designed on autothermal reforming of methane for hydrogen production, and its performance and thermal behavior, that is, based on the reaction mechanism, is numerically investigated by varying the cylinder radius, cylinder spacing, and cylinder layout. Steam methane reforming is a catalytic process and catalyst properties are dictated by the severe operating conditions, that is, temperatures of 450950c and steam partial pressures up to 30 bar. The reactions for the two simultaneous smr mechanisms are shown as equations 1 and 2. Currently, this process is the main route to obtain hydrogen and synthesis gas for ammonia and methanol. Steam methane reforming market global industry analysis. The gas produced by the steam reforming reaction first passes through a shift reactor, where carbon monoxide converts to carbon dioxide and hydrogen.
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